4-tert-Butylbenzoic Acid: Chemical Profile, Properties, and Practical Insights

What is 4-tert-Butylbenzoic Acid?

4-tert-Butylbenzoic Acid stands as an aromatic carboxylic acid with a distinct tert-butyl group on the fourth carbon of the benzene ring, making it distinct among raw chemicals. This molecular structure, C11H14O2 with a formula weight of about 178.23 g/mol, brings stability and certain reactivity that industry experts notice in polymer additives, resins, and diverse organic syntheses. Its solid and crystalline nature means it usually comes in either white flakes, powders, or sometimes pearl-like granules, depending on production conditions and purity requirements during manufacturing. Handling the raw form or any solution demands awareness of its chemical property: it melts just above 164 °C and dissolves best in organic solvents, showing limited water solubility.

Product Appearance and Material States

People working directly with 4-tert-Butylbenzoic Acid see it as a firm, grainy solid at room temperature, displaying a snowy white to off-white color whether in powder, crystalline, or flaked form. These appearances are no accident; they reflect both the high melting point and the loosely cohesive forces between molecules. In specific lab settings or special applications, this acid forms concentrated solutions, often in alcohol or ether, meaning even at the molecular level, its aromatic ring and bulky tert-butyl group affect how it interacts with other substances. Trying to liquefy it usually means raising the temperature or applying high-purity solvents; workers see its powder floating gently, never settling like denser mineral products might.

Chemical Properties and Structure

The backbone of 4-tert-Butylbenzoic Acid, with a benzene ring sporting a carboxylic acid (–COOH) at one end and a tert-butyl (C(CH3)3) at the para position, makes the molecule both sterically hindered and electronically interesting. This structure means it's less reactive toward certain substitutions than plain benzoic acid, useful if one needs a stable additive or an intermediate that resists quick transformation. It has a density of about 1.046 g/cm3, which makes weighing and mixing fairly predictable in a laboratory setting. Any experienced chemist handling it knows it refuses to mix with water as benzoic acid does, highlighting its hydrophobic tert-butyl tail. This resistance to water and strong solubility in hydrocarbons opens doors for its use in oil-based products, including lubricants and specialty coatings.

Specifications and Standard Values

Routine lots of 4-tert-Butylbenzoic Acid show a purity percentage of no less than 99.0%, with trace impurities managed tightly, especially if the product feeds into pharmaceutical or high-performance polymer chains. Moisture limits stay well below 0.5%. Flake or powder selection often depends on application—build-up in extrusion lines favors pearlized solid forms, while solution processing likes finely milled powders for quick dissolution. The acid number and melting point determine suitability more than most other measures, with the acid number reflecting the molar mass and functional group purity directly. For global trade, the HS Code classifies it usually as 29163990 under aromatic monocarboxylic acids, guiding logistics and custom compliance teams during import or export.

Health, Safety, and Hazard Information

Although not acutely toxic at the scale of volatile industrial acids, working with 4-tert-Butylbenzoic Acid means respecting chemical safety. Dust can irritate the respiratory tract, so wearing a properly fitting mask or working under a fume hood becomes second nature. Skin contact for extended periods may cause mild irritation; gloves, goggles, and good ventilation form the basic personal protective approach. It resists ignition, but workers treat large amounts with caution, always following local hazardous chemical guidelines. Waste management focuses on containment—keeping spilled solid or contaminated solvent from drain systems avoids environmental mishaps, since like many aromatic acids, breakdown in the open environment proceeds slowly.

Applications and Solutions for Safer Use

Extensive use of 4-tert-Butylbenzoic Acid stretches across modern industry. In synthetic polymers, it acts as a crystal modifier or chain stabilizer, helping resin solutions keep clarity and performance through molding and processing. As a raw material, it supports specialty adhesives and paints, with its bulky tert-butyl group providing the right chemical "hindrance" to lower reactivity in certain reactions. Down-to-earth, keeping process lines clean, minimizing dust creation during transfer, and tightly labeling all storage bins avoids most workplace mishaps. Training shifts toward hazard recognition, not just rote compliance; all hands familiarize themselves with chemical labels, MSDS sheets, and local emergency contacts to keep any spill or exposure from becoming a bigger issue. For those hoping to replace riskier carboxylic acids, 4-tert-Butylbenzoic Acid promises a less volatile, lower-hazard profile under the right storage and handling routines.

Conclusion

Daily work with 4-tert-Butylbenzoic Acid blends chemical know-how, attention to storage detail, and respect for the properties that make it a mainstay raw material. Meeting industry demand means weighing purity, melting behavior, physical form, and compliance with shipping standards as much as anything else in the chemical supply chain. Done right, this material offers reliability and a manageable risk profile, showing how thoughtful handling and knowledge support safer, more effective plant operations and research initiatives.